| +10.19 | | | — | | | Long-Term Incentive Agreement dated as of December 18, 2019, between Valero Energy Corporation and R. Lane Riggs–incorporated by reference to Exhibit 10.17 to Valero’s annual report on Form 10-K for the year ended December 31, 2019 (SEC File No. 001-13175). | | |
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| +10.20 | | | — | | | Letter Agreement, dated June 18, 2020, between Valero Energy Corporation and Donna M. Titzman–incorporated by reference to Exhibit 10.1 to Valero’s current report on Form 8-K dated June 18, 2020, and filed June 22, 2020 (SEC File No. 001-13175). | | |
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| +10.21 | | | — | | | Form of Stock Unit Award Agreement for Non-Employee Directors (standard)-incorporated by reference to Exhibit 10.01 to Valero’s current report on Form 8-K dated April 30, 2019, and filed May 1, 2019 (SEC File No. 001-13175). | | |
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| +10.22 | | | — | | | Form of Stock Unit Award Agreement for Non-Employee Directors (with one-year hold provision)-incorporated by reference to Exhibit 10.02 to Valero’s current report on Form 8-K dated April 30, 2019, and filed May 1, 2019 (SEC File No. 001-13175). | | |
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| 10.23 | | | — | | | Fourth Amended and Restated Revolving Credit Agreement, dated as of March 19, 2019, among Valero Energy Corporation, as Borrower; JPMorgan Chase Bank, N.A., as Administrative Agent; and the lenders named therein–incorporated by reference to Exhibit 10.1 to Valero’s current report on Form 8-K dated March 19, 2019, and filed March 19, 2019 (SEC File No. 001-13175). | | |
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| +10.24 | | | — | | | Form of Amended and Restated Performance Share Agreement (2020 grant–second and third tranches)–incorporated by reference to Exhibit 10.01 to Valero’s quarterly report on Form 10-Q for the quarter ended March 31, 2021 (SEC File No. 001-13175). | | |
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| +10.25 | | | — | | | Form of Performance Share Agreement (2021 grant and current)–incorporated by reference to Exhibit 10.02 to Valero’s quarterly report on Form 10-Q for the quarter ended March 31, 2021 (SEC File No. 001-13175). | | |
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| *+10.26 | | | — | | | Form of Restricted Stock Agreement (current). | | |
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| 14.01 | | | — | | | Code of Ethics for Senior Financial Officers–incorporated by reference to Exhibit 14.01 to Valero’s annual report on Form 10-K for the year ended December 31, 2003 (SEC File No. 001-13175). | | |
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| 14.02 | | | — | | | Valero Energy Corporation Code of Business Conduct and Ethics–incorporated by reference to Exhibit 14.1 to Valero’s current report on Form 8-K dated January 26, 2021, and filed January 29, 2021 (SEC File No. 001-13175). | | |
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| *21.01 | | | — | | | Valero Energy Corporation subsidiaries. | | |
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| 22.01 | | | — | | | Subsidiary Issuer of Guaranteed Securities–incorporated by reference to Exhibit 22.01 to Valero’s annual report on Form 10-K for the year ended December 31, 2020 (SEC File No. 001-13175). | | |
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| *23.01 | | | — | | | Consent of KPMG LLP dated February 22, 2022. | | |
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| *24.01 | | | — | | | Power of Attorney dated February 22, 2022 (on the signature page of this Form 10-K). | | |
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| *31.01 | | | — | | | Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal executive officer. | | |
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| *31.02 | | | — | | | Rule 13a-14(a) Certification (under Section 302 of the Sarbanes-Oxley Act of 2002) of principal financial officer. | | |
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| **32.01 | | | — | | | Section 1350 Certifications (under Section 906 of the Sarbanes-Oxley Act of 2002). | | |
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| 99.01 | | | — | | | Audit Committee Pre-Approval Policy–incorporated by reference to Exhibit 99.01 to Valero’s annual report on Form 10-K for the year ended December 31, 2020 (SEC File No. 001-13175). | | |
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| ***101.INS | | | — | | | Inline XBRL Instance Document–the instance document does not appear in the Interactive Data File because its XBRL tags are embedded within the Inline XBRL document. | | |
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| ***101.SCH | | | — | | | Inline XBRL Taxonomy Extension Schema Document. | | |
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| ***101.CAL | | | — | | | Inline XBRL Taxonomy Extension Calculation Linkbase Document. | | |
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| ***101.DEF | | | — | | | Inline XBRL Taxonomy Extension Definition Linkbase Document. | | |
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| ***101.LAB | | | — | | | Inline XBRL Taxonomy Extension Label Linkbase Document. | | |
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